Facile Synthesis of (C <sub>6</sub> F <sub>5</sub> ) <sub>2</sub> BBr and (C <sub>6</sub> F <sub>5</sub> ) <sub>2</sub> BX(OEt <sub>2</sub> ) (X=Cl, Br) using Hydrogen Halides and Piers’ Borane

نویسندگان

چکیده

We report the facile and efficient synthesis of common electrophilic haloboranes via a protonolysis reaction between Piers’ borane, HB(C6F5)2, H−X (X=Cl, Br). This route benefits from fast times, easy setup, minimal workup to yield analytically pure etherates, (C6F5)2BCl(OEt2) (1) (C6F5)2BBr(OEt2) (2), as well ether-free tri-coordinate species, (C6F5)2BBr (3).

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ژورنال

عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie

سال: 2023

ISSN: ['0044-2313', '1521-3749']

DOI: https://doi.org/10.1002/zaac.202300007